| Cayenne to Sangeorz-Bai | 5,360.82 mi (8,627.40 km) |
| Cayenne to Sannicolau Mare | 5,157.88 mi (8,300.80 km) |
| Cayenne to Santana | 5,202.82 mi (8,373.13 km) |
| Cayenne to Satu Mare | 5,281.54 mi (8,499.82 km) |
| Cayenne to Scobinti | 5,465.86 mi (8,796.45 km) |
| Cayenne to Scornicesti | 5,334.38 mi (8,584.86 km) |
| Cayenne to Sebes | 5,297.47 mi (8,525.45 km) |
| Cayenne to Seini | 5,299.35 mi (8,528.49 km) |
| Cayenne to Sfantu-Gheorghe | 5,402.80 mi (8,694.97 km) |
| Cayenne to Sibiu | 5,323.96 mi (8,568.09 km) |
| Cayenne to Sighetu Marmatiei | 5,328.86 mi (8,575.97 km) |
| Cayenne to Sighisoara | 5,357.58 mi (8,622.20 km) |
| Cayenne to Simeria | 5,269.82 mi (8,480.95 km) |
| Cayenne to Sinaia | 5,388.25 mi (8,671.55 km) |
| Cayenne to Slatina | 5,324.30 mi (8,568.63 km) |
